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For reproduction of material from NJC: Reproduced material should be attributed as follows: Back to tab navigation Download options Please wait The reaction proceeded through a two-fold intramolecular nucleophilic addition O-nucleophilic addition and then C aryl -nucleophilic addition to a vinylidenecyclopropane moiety to give a highly strained intermediate and subsequent retro-Diels—Alder addition.

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In all cases the Ref. The reaction mechanism has been investigated on the basis of a deuterium labeling experiment, mass kotfa investigation and DFT calculation.

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